![]() Music Careerįreddy had released around 15 albums to date. If you prefer to have the girls on stage with you, you can do that," he added.įreddy is an artist under Cool Money Entertainment alongside Slezzy Bezzy. "They book me because I used to be there, before the rap, having fun," Freddy shared to Dallas Observer in 2018 about his perception of performing at strip clubs. He considers strip clubs to be no different than other stages he performed at. Additionally, he is famous for playing at strip clubs and nightclubs. Playing music at Strip/ Night Clubsįreddy is a frequent performer at Dallas-Fort Worth. He had accumulated a sizable collection of self-released mixtapes, drawing on his experiences as a poor kid and keen hustler. In addition to a three-volume series that began with Trapboy Freddy Krueger in 2015, Freddy's self-released collection included No Feelings (2018), Black Migo (2017), and many more. Early Careerįrom the streets, selling drugs to strip clubs to music, Freddy had gone through everything in life before he could attain 22. ![]() At the age of 21, Freddy decided to restructure his lifestyle and pursue a career in music, specifically in hip-hop and trap music.įreddy had received his high school education from David W Carter High school. ![]() Therefore, from an early age, Freddy had to fulfill the responsibility of a man-figure of the house.Īs an adolescent, he spent three years back and forth in jail. He was raised without a father, and his elder brother was paralyzed in a car accident. Just-Ice Talks Gangsta Rap, Drops New Music, Says Heavy D Jacked Him, Gives Self-Destruction Secrets Early life and Educationĭevarius Dontez Moore, popularly known as, Trapboy Freddy was born on 14 January 1992 in Oak Cliff, Dallas, Texas. He was the youngest of his five siblings, three of whom were his sisters. Since then, he has released several albums Cme or Nothing (2017), Overtime (2017), Trap boy Freddy Krueger 2 (2016), 4th quarter (2016), while some of his hit singles include, 'Lil Quita' (2019), 'Go' (2018), 'Guardian Angel' (2020) and among many others. Furthermore, he spent three years in and out of jail before deciding to pursue a musical career at the age of 21. He spent most of his childhood on the streets. Trapboy Freddy is a rapper, songwriter, hip-hop, and trap musician. Trapboy Freddy is an American hip-hop and trap musician credited for albums 'Distraction' (2021), 'Big Trap' (2020), and 'Trapboy Freddy Krueger' (2015). Ever since then, he actively got engaged in making music. As it garnered the attention of substantial audiences, Freddy released a video that he made of his own, and it did pretty well. He then recorded and posted a song on the internet and began promoting it. As a teenager, Freddy enjoyed free-styling and had no vision about choosing a kind of music.
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![]() ![]() Substituted guar gum has been proved environmental friendly thickener as compared to synthetic thickeners. The synthesized guar gum derivatives, being the natural thickners, have been used in textile printing technology. The DS was determined quantitatively by titration method for each derivative. Guar derivative with variable degree of substitution (DS) were prepared and were confirmed by Fourier transform infrared (FTIR) spectroscopy. The reaction conditions were also optimized during the course of experiment. This study focusses on the synthesis of carboxymethyl guar gum (CMG) via monochloroacetic acid under alkaline conditions. This study, shows the process has dramatically impacted the fluid properties, commercial worth, and economic producibility of the investigated oil accumulations in the basin. Nevertheless, the possibility of oil mixing cannot be excluded, because biodegradation is progressive and is ongoing. However, biomarker fingerprints of the oils lack evidence of in-reservoir mixing of biodegraded and non-biodegraded oils. Total ion chromatograms of well 1 and 2 from Northern depobelt, show presence of LMW alkanes, co-existing side by side with UCM, suggesting multiple charges. This influenced shifts in the ‘primary compositions’ of oils probably from paraffinic or paraffinic-naphthenic oils to aromatic-naphthenic oils. Biodegradation levels of the considered oils range from light to moderate, based on Peters and Moldowan scale. ![]() Saturated, aromatic, resins, and asphaltenes (SARA) compositions and low saturate/aromatic ratio confirmed evidence of biodegradation. GC results indicate variable loss of low molecular weight (LMW) alkanes, besides the presence of unresolved complex mixture (UCM). Ten oil samples from onshore-offshore fields were analyzed using gas chromatography (GC) and GC-mass spectrometry (GC-MS) methods. This study aimed to examine the compositional changes resulting from biodegradation, fathom the extent of degradation, and provide clues for interpreting the evolution and the overall effects on the quality of the oils. So, this study suggested that the faecal sludge was an environment-friendly low-cost replacement of microalgae for high-quality biocrude production towards a sustainable biorefinery approach. Finally, the higher energy recovery of 85.6% and lower energy consumption ratio of 0.58 for MA25FS75 confirmed the net energy positivity system. ![]() In addition, the biocrude maturity and intensity analysis suggested higher A-factor and lower C-factor for MA25FS75, which indicated a high-quality crude property. Among the various ratios, the co-hydrothermal liquefaction of MA25FS75 (25% microalgae: 75% faecal sludge) sample showed the highest biocrude yield of 38% with a lighter hydrocarbon fraction of 43% (kerosene 15% and diesel 28%) and HHV of 33.8 MJ/Kg. Hence, this study explored the effect of substituting microalgal biomass with faecal sludge (wet-waste) at different ratios (100:0, 25:75, 50:50, 75:25, and 0:100) for biocrude production through hydrothermal liquefaction. Keyword: Crude Oil, Treated, Untreated ASTM, BS&W, OAPI, Physiochemical Properties, Oil Field, Standards.Ĭultivation and harvesting of microalgal biomass are energy-intensive and expensive processes. the importance of crude oil's physicochemical parameters cannot be overstated in chemical engineering analysis, shipping, transportation, optimizing, storage, as well as the pricing of crude oil at the point - of - sale. The above physical and chemical properties were determined using Standard test method and 0API. Comprehensive review of the physicochemical characteristics properties of various oil oils from Niger Delta oil wells ( Ogbele and Kokori oil fields, respectively) shows the following BS&W (percent) values for un -treated and dry crude to be 34 percent and 44 percent, respectively in comparison to un - treated crude oil and oAPI 34.97 and 35.87 at 53☏ respectively.Treated crude oil has a BS&W of < 1 percent. Prior to actually sales, the physical and chemical properties of these crude oils must be addressed in attempt to reach standards. The BS&W standard for the shipment of crude oil to a pipeline company is one %. Nigeria's Niger-Delta is a rich source of crude oil, but it consists unwanted contaminants such as basic sediments & water that cannot be avoided in the petroleum sector. In this research, the characteristics of crude oil from two distinct oil fields in the Niger Delta were compared. Subscribe to our new food newsletter, Stuffed, to get Denver food and drink news sent straight to your inbox.At a preview experience, the brunch menu showcased a double-digit list of delights. This is our restaurant group, and every decision we make benefits our future.” “It’s a reward for people beyond a thank you, or a bonus check,” Cucci said. When New Belgium Brewing sold to Lion little World Beverages in 2009, more than 300 employee owners received at least $100,000. It’s an amount that some employee-owners could also see in their futures, if the success of Colorado’s other large food and beverage ESOP is any indication. A new non-profit wing of Edible Beats will choose a local cause to support over the next five years, with the goal of raising $1 million. “As an industry we can take better care of our staff,” Cucci said. There’s been biannual profit sharing, and more recently, lifestyle spending accounts created for wellness expenses not typically covered by health insurance. For the past eight years, the restaurant group has offered its management 401k plans with up to 5% company matching. He hopes the move further “personifies” Edible Beats’ existing culture and values. This decades-old Aurora restaurant has some of the best wontons and dumplings in town “We can do the ESOP and reward the people who have been on this journey.” Related Articles “We thought, what a great thing,” Cucci said. Workers become fully vested after five years with the company if they have already been with Edible Beats for at least five years, that back-tenure counts toward ownership status. By February, Cucci switched to 100% employee-ownership, with 330 employees enrolled in the program. It cost him more than $400,000 to set up the ESOP and will continue to cost between $75,000 and $100,000 to maintain, Cucci estimated.īut the benefits include significant federal and local tax breaks and, hopefully, a viable business model for years to come. (James Florio, Provided by Edible Beats)įor Edible Beats, the process took five years, including a pause once the pandemic started, during which Cucci stopped trying to secure a bank loan for the restructuring process. The music venue, bar and restaurant is part of a group of local restaurants that are now employee-owned. James Florio, Provided by Edible BeatsOphelia’s Electric Soapbox reopened in Denver in April 2022 after a long pandemic closure and a redesign of the interior. “It’s really, pretty much non-existent,” Cucci said, adding, “the process is by no means easy, simple or effortless.” Of around 6,000 ESOPS in the U.S., just 1% are in the accommodation and food services industry. Jared Polis said in a press release on Wednesday.Įdible Beats joins around 100 other Colorado-based employee-owned companies, according to the National Center for Employee Ownership. ![]() “We are saving employee-owned companies money with up to $100,000 in tax credits on qualifying costs of converting, and I am proud to congratulate Edible Beats for taking this exciting step,” Gov. Colorado’s Office of Economic Development and the Governor’s office are also behind the plan. But with employee-ownership, “the ownership wins, the employees win and, in theory, the guests win.”Īt a time when restaurants are coming off of a shattering industry-wide crisis, and are still struggling to find and retain workers and keep menu prices down amid inflation, Cucci thinks the employee-ownership model is an intriguing, if initially costly, solution. ![]() The idea of selling to an outside investor, or even to one or two high-ranking employees didn’t sit well with him. “When we went over some longer term (succession plans), none of them seemed attractive,” Cucci added. Friday, October 14th 2022 Home Page Close Menu ![]() Step-2: Divide the increased value by the original number and further multiply the answer by 100. This tells you that you get #"25.7 g"# of rubidium nitrate for every #"100 g"# of the solution. Thus to calculate the percentage increase we will follow two steps: Step-1: Calculate the difference i.e. #color(darkgreen)(ul(color(black)("% m/m" = "25.7% RbNO"_3)))# The formula to calculate your weight loss percentage is: lbs lost divided by starting weight. This means that the solution's percent concentration by mass is equal to So, you know that you have #"346.56 g"# of rubidium nitrate in #"1346.56 g"# of the solution, so you can say that #"100 g"# of this solution will contain The solution composition can be described in mass percentage which shows the mass of solute present in a given mass of solution. This means that the total mass of the sample is equal to Use the molar mass of the solute to convert the number of moles to grams As we've said, this sample will also contain #2.35# moles of rubidium nitrate. ![]() To make the calculations easier, pick a sample of this solution that contains exactly #"1 kg" = 10^3 quad "g"# of water. This tells you that this solution contains #2.35# moles of rubidium nitrate, the solute, for every #"1 kg"# of water, the solvent. Now, you know that the solution has a molality equal to #"2.35 mol kg"^(-1)#. the solution's percent concentration by mass, #"% m/m"#. The formula weight is simply the weight in atomic mass units of all the atoms in a given formula.Your goal here is to figure out the number of grams of solute present for every #"100 g"# of the solution, i.e. When calculating molecular weight of a chemical compound, it tells us how many grams are in one mole of that substance. The percentage by weight of any atom or group of atoms in a compound can be computed by dividing the total weight of the atom (or group of atoms) in the formula by the formula weight and multiplying by 100.įinding molar mass starts with units of grams per mole (g/mol). If the formula used in calculating molar mass is the molecular formula, the formula weight computed is the molecular weight. This site explains how to find molar mass. The reason is that the molar mass of the substance affects the conversion. The theoretical (actual) percent hydration (percent water) can be calculated from the formula of the hydrate by dividing the mass of water in one mole of. To complete this calculation, you have to know what substance you are trying to convert. Using Molar Mass calculations to figure the percentage that. Using the chemical formula of the compound and the periodic table of elements, we can add up the atomic weights and calculate molecular weight of the substance.Ī common request on this site is to convert grams to moles. The percentage by weight of any atom or group of atoms in a compound can be computed by dividing the total weight of the atom (or group of atoms) in the formula. Objective 4: Calculate the percentage composition of a given chemical compound. For bulk stoichiometric calculations, we are usually determining molar mass, which may also be called standard atomic weight or average atomic mass. ![]() This is not the same as molecular mass, which is the mass of a single molecule of well-defined isotopes. This is how to calculate molar mass (average molecular weight), which is based on isotropically weighted averages. New number (Previous Year Sale): 4,950,000. Old Number (Current Year Sale): 5,475,000. The atomic weights used on this site come from NIST, the National Institute of Standards and Technology. First of all, we will calculate the change in a sale by applying the formula: Use the below-given data for the calculation. These relative weights computed from the chemical equation are sometimes called equation weights. In chemistry, the formula weight is a quantity computed by multiplying the atomic weight (in atomic mass units) of each element in a chemical formula by the number of atoms of that element present in the formula, then adding all of these products together.įormula weights are especially useful in determining the relative weights of reagents and products in a chemical reaction. Lightning GPS All-in-One Magnetic Cellular LTE GPS Tracker with 140 Day Battery. Top 3 Features Of Everlast Nano Cheating Wife Tracker, Longest Battery Life (138 Days+) Fast Updates, Month-To-Month Service Plans Starting at $24.95, Save $100.00 on this long-lasting vehicle tracking device by CLICKING HERE! Sponsored Sponsored Sponsored. Up to 36 hours of battery life, plus all the Apple Watch features that help you stay healthy, safe, and connected. The Jiobit Next GPS tracker for kids stands out for its 10-day battery life, learning technology, and small size. Best Overall and CR Best Buy: Tractive GPS Dog LTE. Inside this weatherproof housing, a strong 80 lb battery gives a whopping 120 total hours of battery life used when the unit is in motion, giving you weeks of tracking time while it remains in the field. dedicated GPS trackers for kids in terms of. With the long-life battery power, the GPS tracker can stand by and constantly track your vehicle after it is installed. This asset GPS tracker has unlimited uses for personal and business applications. Long Beach, CA Virginia Beach, VA Miami, FL Oakland, CA Minneapolis, MN Tampa, FL Arlington, TX. Its data is protected by multiple layers of encryption, and Jiobit's the only COPPA-certified device on our list. Here are the three of the best GPS trackers for dementia patients. For the GPS tracker to work, it requires a power connection. There are also battery powered GPS trackers with a long 5-year battery life. These GPS trackers are for trailers & equipment. Free shipping Free shipping Free shipping. 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The long-life battery allows you to track items that you may not be able to access for a while. ![]() The digital encryption on the Ailunce HD1 isn’t great, and while that’s not as much of an issue for some people, it’s not 100 percent reliable, and it’s only compatible with other Ailunce HD1s. Topping this off, the HD1s full-color backlit screen and ability to swap on aftermarket high-end antennas mean that this radio can be used for more emplaced communications with much larger antennas, which is essential at lower frequencies. The fully-digital nature of the Ailunce HD1 also means that you can store things like contacts and talk groups, rather than having to manually enter frequencies every time, and even offers a modicum of encryption to not only keep your communications private, but also ensure voice clarity. That’s not fully waterproof, but if you want to be able to pull your radio out of a waterproofing bag or box while on the water to make a call, you can do so with a bit more confidence. It’s only IP67, so it’s immersible in a meter of water for 30 minutes. The water resistance is another important point for this radio, allowing you more peace of mind, especially if your journeys take you near or across the water. This is a full-featured radio with many capabilities that make it, overall, the best walkie-talkie for long range use.Ĭalling an item a powerhouse is a common way to describe it as “good,” but for the Ailunce HD1, it’s a reference to the bonkers output power of 10 watts, which might not be much compared to military radios or dashboard-mounted radios in a vehicle, but for a pocket-sized handset, it’s very good, especially at this price point. The HD1 is capable of being programmed using included computer software, meaning that you can load several radios with frequency charts and contact lists to ensure 100 percent compatibility. Digital frequencies allow for clearer voice quality, longer transmission ranges, and the ability to send things like GPS data, text messages, and encrypted transmissions. This is due to the fact that it’s a Digital Mobile Radio, or DMR. The Ailunce HD1 isn’t just a good walkie talkie, it’s one of the best walkie talkies, and particularly one of the best walkie talkies for long-distance communication. ![]() ![]() Go with the Ailunce HD1.” Those were the words that my friend Ian, who recently finished his stint as an Army signals intelligence soldier and who is an amateur radio enthusiast, told me when I asked him what he recommended for handheld radios for personal usage. “If you’re really serious about radios, don’t worry about Baofengs. Ultimately, we stretched these radios to the limits, and I drew on the years of experience that the people I interviewed had to ensure that these choices reflected the little things that you pick up through long-term use in the elements and various terrains. In addition, I experimented extensively with the radios on this list, as well as the antennas that are needed to capitalize on the radio frequencies used to get the long-range capabilities that readers of this article are looking for.Īnd finally, I coordinated with HAM radio operators to test the full potential of these radios, since using certain frequencies and encryption requires a HAM license to do without legal trouble. In testing these radios for this article, I wasn’t content to trust my own limited knowledge on the topic of long-range communication, so I consulted with Marine Corps communication specialists, Army signal soldiers, amateur HAM radio operators, and experts on digital signal transmission. Best Long-Range Antenna: Abbree Foldable tactical antenna.Because when you’re in the mountains of West Virginia, the forests of the Pacific Northwest, or the scorching bright heat of the Sonoran Desert in California, cell reception isn’t always reliable, but emergency assistance can be imperative. Thankfully, you, the average Joe or Josephine, have access to better comms than the Russian military, and with this article, your own radio, and maybe a HAM radio class or two, you will have communications for your next wilderness adventure. This is because they did not have properly established comms, and were not using proper encryption keys, like modern militaries. For those listening, it’s led to hilarious comms exchanges, but it’s also been linked to the deaths of several Russian generals. One of the most amusing things about watching Russia’s invasion of Ukraine in early 2022 was their use of unencrypted Baofeng radios as their primary mode of communication. Comms are dark sorcery, and “long-range walkie talkies” can sound like an oxymoron, but the best long-range walkie talkies are actually quite simple to use, based on their ability to address different frequencies, accept better antennas, and increase output power. ![]() It is one of those plugins that do everything for you. The fact that you really don’t need any prior knowledge for this is what makes BackupBuddy stand out. A very easy to use backup plugin for WordPress, which chooses almost all settings itself and therefore makes it especially easy for you to quickly and uncompromisingly create a backup of your entire WordPress blog. BackupBuddy BackupBuddy Premium WordPress Backup Plugin.ĭeveloper iThemes is primarily known for its WordPress Security plugin, and the company’s other products have become extremely popular as well.
![]() You need to add a playlist from your IPTV provider to be able to watch it. It helps you on how to fix all software problems on android tv box like. Philips, Sharp, Toshiba, and Sony are just a few of the manufacturers that have this operating built-in as standard. IMPORTANT! Smarters Player Lite doesn't provide any kind of media content. In this guide we show you how to update android tv box from USB to latest firmware. Android TV can be found on a huge number of smart TVs. Ability to open “ List of episodes” on the Video Player Ability to open the channel list on the Video Player Load Your Playlist Or File/URL Improvements Speed Test facility Integrated and VPN Integration If you are Hisense, TCL, Sceptre, Phillips. Support: Local Audio / Video files Playing For playing such videos on an Android Smart TV, you would need a video player that supports different video formats. Support: Recently Added Movies & Series Ability to change the buffer size for the VIDEO Player Native Player and Built-in Player Added Watch LIVE sporting events, Hollywood blockbusters, evergreen movies, TV series, documentaries and cartoons on your own Android TV boxes and Smart TV. Jellyfin runs in browsers, Android and iOS devices, Android TV. Support Xtream Codes API, M3U URL & Playlist, Local audio/video files m3u format, the music directory contains music. Live, Movies, Series, and Radio Streaming Supported Android TV ist ein Betriebssystem für Smart-TV-Plattformen und bietet Fernsehgeräten und Set-Top-Boxen Zugriff auf die Google Play-Services. Smarters Player is the lite version of "IPTV Smarters Pro" with all the basic features unlocked. Product Specifications Smart Player, Media/Music play for USB Device Chromecast, A technology that lets you cast your favorite entertainment and apps from. The Smarters Player App is a fabulous media player that allows end-users to play their content like Live TV, VOD, Series, and Local audio/Video files supplied by them on their Android Phones, Android TVs, FireSticks, and other android devices. |
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